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In the above reaction, explain why the silver ions form a new compound with the chloride ions but not with the sodium ions.

Question

In the above reaction, explain why the silver ions form a new compound with the chloride ions but not with the sodium ions.

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Solution

In order to answer this question, we first need to understand the nature of the ions involved. Silver ions (Ag+) have a positive charge, while both chloride ions (Cl-) and sodium ions (Na+) have negative and positive charges respectively.

  1. The formation of compounds is primarily driven by the electrostatic attraction between ions of opposite charges. In this case, the positively charged silver ions (Ag+) are attracted to the negatively charged chloride ions (Cl-), leading to the formation of silver chloride (AgCl).

  2. Sodium ions (Na+), on the other hand, are also positively charged, just like silver ions (Ag+). Since like charges repel each other, there is no attraction between the sodium ions and the silver ions. Therefore, they do not form a compound.

  3. Additionally, in a solution, sodium ions (Na+) and chloride ions (Cl-) exist as separate entities. When silver ions (Ag+) are introduced, they have a higher affinity for chloride ions (Cl-) than sodium ions (Na+) do. This is due to the fact that the formation of silver chloride (AgCl) is more energetically favorable than the formation of sodium chloride (NaCl). As a result, the silver ions displace the sodium ions, forming a new compound with the chloride ions.

  4. Lastly, silver chloride (AgCl) is insoluble in water, which drives the reaction to completion. The formation of a precipitate (solid) from ions in solution is a key driving force in many chemical reactions. In contrast, both sodium chloride (NaCl) and sodium nitrate (NaNO3) are soluble in water, so they remain in solution and do not form a precipitate.

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