S=O bonds have inefficient orbital overlap making the sulfur atom electron-poor and electrophilic.Select answer from the options belowTrueFalse
Question
S=O bonds have inefficient orbital overlap making the sulfur atom electron-poor and electrophilic.
Select answer from the options below:
- True
- False
Solution
Analyzing the Statement
-
Understanding S=O Bonds:
- Sulfur (S) can form multiple bonds, including double bonds with oxygen (O). In a double bond such as S=O, the overlap of orbitals is crucial in determining the electronic properties of the molecule.
-
Orbital Overlap Efficiency:
- The efficiency of orbital overlap affects the electron density around the atoms involved in the bond. Poor overlap typically leads to a lower density of electrons around the less electronegative atom.
-
Characterization of Sulfur:
- Sulfur is less electronegative than oxygen, leading to a partial positive charge on sulfur when bonded to oxygen. This behavior indicates that the sulfur atom can act as an electrophile, attracting nucleophiles.
Conclusion
Given that S=O bonds indeed have inefficient orbital overlap, resulting in sulfur being electron-poor and electrophilic, the statement is:
Final Answer
True
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