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0.360 g of a diatomic gas occupies 125.0 mL at 23.0o C and 750. torr. What is the molar mass of the gas? What diatomic gas is it?

Question

0.360 g of a diatomic gas occupies 125.0 mL at 23.0°C and 750. torr. What is the molar mass of the gas? What diatomic gas is it?

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Solution

To solve this problem, we need to use the ideal gas law equation, which is PV = nRT. However, we need to find the molar mass, so we will rearrange the equation to solve for n (number of moles), which is n = PV/RT.

First, we need to convert the given values to the appropriate units:

  • Pressure (P) is given in torr, but we need it in atmospheres. We know that 1 atm = 760 torr, so P = 750 torr * (1 atm / 760 torr) = 0.98684 atm.
  • Volume (V) is given in mL, but we need it in liters. We know that 1 L = 1000 mL, so V = 125.0 mL * (1 L / 1000 mL) = 0.125 L.
  • Temperature (T) is given in Celsius, but we need it in Kelvin. We know that T(K) = T(C) + 273.15, so T = 23.0 C + 273.15 = 296.15 K.
  • R is the ideal gas constant, which is 0.0821 Latm/(Kmol).

Now we can substitute these values into the equation:

n = PV/RT = (0.98684 atm * 0.125 L) / (0.0821 Latm/(Kmol) * 296.15 K) = 0.00501 mol.

The molar mass of a substance is the mass of one mole of that substance. It is given by the formula:

Molar mass = mass / number of moles

Substituting the given mass (0.360 g) and the calculated number of moles (0.00501 mol), we get:

Molar mass = 0.360 g / 0.00501 mol = 71.86 g/mol.

This molar mass is close to the molar mass of chlorine gas (Cl2), which is 70.90 g/mol. Therefore, the diatomic gas is likely to be chlorine.

This problem has been solved

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