Describe a corrosion protection method with proper cell reactions and a suitablediagram to protect an underground pipe line.
Question
Describe a corrosion protection method with proper cell reactions and a suitable diagram to protect an underground pipe line.
Solution
One of the most common methods for protecting underground pipelines from corrosion is cathodic protection. This method involves connecting the metal to be protected to a more easily corroded "sacrificial metal" to act as the anode. The sacrificial metal then corrodes instead of the protected metal.
Here are the steps involved in this process:
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Selection of Anode: The first step is to select a suitable sacrificial anode. This is typically a metal that is more reactive than the metal of the pipeline. Common choices include zinc, aluminum, or magnesium.
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Connection: The sacrificial anode is then electrically connected to the pipeline. This can be done using a conductive wire. The anode and pipeline form a galvanic cell, with the anode being the negative electrode and the pipeline being the positive electrode.
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Burying the Anode: The anode is then buried in the ground near the pipeline. The soil acts as the electrolyte in this galvanic cell.
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Corrosion: Over time, the sacrificial anode corrodes, while the pipeline remains protected. The anode needs to be replaced periodically to ensure continued protection.
The cell reactions involved in this process are as follows:
At the anode (sacrificial metal), the metal atoms lose electrons and become ions. This is an oxidation reaction. For example, if the anode is made of magnesium, the reaction is:
Mg(s) → Mg2+(aq) + 2e-
At the cathode (pipeline), the electrons from the anode are taken up by the metal atoms, preventing them from becoming ions. This is a reduction reaction. For example, if the pipeline is made of iron, the reaction is:
Fe2+(aq) + 2e- → Fe(s)
The overall cell reaction is:
Mg(s) + Fe2+(aq) → Mg2+(aq) + Fe(s)
The diagram for this process would show the sacrificial anode connected to the pipeline by a wire, with both the anode and pipeline buried in the ground. The anode would be labeled as the site of oxidation, and the pipeline would be labeled as the site of reduction. The flow of electrons from the anode to the pipeline would also be indicated.
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