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Which is not correctly matched ?XeO3 – Trigonal bipyramidalClF3 – bent T-shapeXeOF4 – Square pyramidalXeF2 – Linear shape

Question

Which is not correctly matched ?

  • XeO3 – Trigonal bipyramidal
  • ClF3 – bent T-shape
  • XeOF4 – Square pyramidal
  • XeF2 – Linear shape
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Solution

To determine which of the given molecular shapes is not correctly matched, we will evaluate each one based on the VSEPR (Valence Shell Electron Pair Repulsion) theory.

  1. XeO₃ – Trigonal bipyramidal: This is incorrect. Xenon trioxide (XeO₃) has a pyramidal shape due to the presence of lone pairs on the xenon atom. The correct shape is trigonal pyramidal, not trigonal bipyramidal.

  2. ClF₃ – Bent T-shape: This is correct. Chlorine trifluoride (ClF₃) has a T-shaped geometry because there are three fluorine atoms and two lone pairs on the chlorine atom.

  3. XeOF₄ – Square pyramidal: This is correct. Xenon oxyfluoride (XeOF₄) features a square pyramidal geometry with four fluorine atoms and one oxygen atom around the xenon, along with one lone pair.

  4. XeF₂ – Linear shape: This is correct. Xenon difluoride (XeF₂) has a linear molecular geometry owing to its two fluorine atoms and three lone pairs.

Final Answer

XeO₃ – Trigonal bipyramidal is not correctly matched; it should be trigonal pyramidal.

This problem has been solved

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