Starting from the equation for the matter wave of a free particle, derive a plausible form of operator for the momentum
Question
Starting from the equation for the matter wave of a free particle, derive a plausible form of operator for the momentum
Solution
The wave function of a free particle is given by the de Broglie relation:
ψ = A * exp(i(kx - ωt))
where k is the wave number, ω is the angular frequency, x is the position, t is the time, and i is the imaginary unit.
The momentum of the particle is given by the de Broglie relation:
p = h * k
where h is Planck's constant.
We can express the wave number k in terms of the momentum p and Planck's constant h:
k = p / h
Substituting this into the wave function gives:
ψ = A * exp(i(px/h - ωt))
Now, we want to find an operator that, when applied to the wave function, gives the momentum of the particle. The derivative of the wave function with respect to x is:
dψ/dx = i * p/h * A * exp(i(px/h - ωt))
= i * p/h * ψ
Solving for p gives:
p = h/i * dψ/dx
This suggests that a plausible form for the momentum operator is:
P = -i * h * d/dx
This operator, when applied to the wave function, gives the momentum of the particle.
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