One mole of 1,2-dibromopropane on treatment with X moles of NaNH2 followed by treatment with ethyl bromide gave a pentyne. The value of X is
Question
One mole of 1,2-dibromopropane on treatment with X moles of NaNH2 followed by treatment with ethyl bromide gave a pentyne. The value of X is
Solution
The reaction of 1,2-dibromopropane with NaNH2 results in the formation of a terminal alkyne through a process known as double dehydrohalogenation.
Here are the steps:
-
The first mole of NaNH2 (sodium amide) removes a hydrogen and a bromine atom from 1,2-dibromopropane, resulting in the formation of a bromopropene and ammonia.
-
The second mole of NaNH2 then removes the remaining hydrogen and bromine atom, resulting in the formation of a propyne.
-
The propyne is then treated with ethyl bromide, which adds an ethyl group to the terminal carbon of the propyne, resulting in the formation of a pentyne.
Therefore, the value of X is 2, as two moles of NaNH2 are required for the reaction to proceed.
Similar Questions
NaNH2 is too strong a base to do a dehydrohalogenation of a geminal dihalide.Select answer from the options belowTrueFalse
The reaction of XeF4 and O2F2 at 143 K give a xenon compound (P). The number of mole of HF produced by the complete hydrolysis of 1 mol of P is___
What is the molarity of 409.55 mL of solution in which 4.2 moles of sodium bromide is dissolved?
What would be the product after reducing 3-pentanone?Question 5Answera.3-pentanolb.Propanal + Ethanec.Pentane + CO2d.3-methylpentane
Which of the following is/are the best casting solution solvents? dimethyl acetamide. dimethyl formamide N-methyl pyrrolidone all the above
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.