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does reduction/oxidation occur at the anode in electrochemistry- a level chemistry ocr a

Question

Does reduction/oxidation occur at the anode in electrochemistry - A Level Chemistry OCR A?

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Solution

In electrochemistry, the anode is the electrode where oxidation occurs. Oxidation is the process of losing electrons, and it always takes place at the anode in both electrolytic (where electrical energy is used to cause a non-spontaneous reaction) and galvanic/voltaic (where a spontaneous reaction produces electrical energy) cells.

Here's a step-by-step explanation:

  1. In an electrochemical cell, there are two electrodes: the anode and the cathode. The anode is defined as the electrode where oxidation occurs, while the cathode is where reduction occurs.

  2. Oxidation is the process where a substance loses electrons. This is often remembered by the acronym 'OIL RIG' - Oxidation Is Loss (of electrons), Reduction Is Gain (of electrons).

  3. In an electrolytic cell, the anode is positively charged because it attracts the negatively charged ions (anions) from the solution. These anions give up their extra electrons (get oxidized) at the anode.

  4. In a galvanic or voltaic cell, the anode is negatively charged. It is the site of oxidation where the substance loses electrons that are then transferred through the wire to the cathode.

  5. Therefore, regardless of the type of cell, oxidation always occurs at the anode in electrochemistry.

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