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During the borax bead test with CuSO4, a blue green colour of the bead was observed in oxidising flame due to the formation ofCu3B2CuCu(BO2)2CuO

Question

During the borax bead test with CuSO4, a blue green colour of the bead was observed in oxidising flame due to the formation of

Cu3B2CuCu(BO2)2CuO Cu_3B_2CuCu(BO_2)_2CuO

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Solution

The borax bead test is a qualitative test used in inorganic chemistry to detect the presence of certain metals. The test involves dipping a loop of wire in a solution of the metal salt, then heating the loop in a flame until it is red hot. This causes the metal ions to react with the borax to form a colored bead.

In the case of CuSO4, the bead will turn a blue-green color in an oxidizing flame. This is due to the formation of copper borate (Cu3B2O6) and copper oxide (CuO).

Here are the steps:

  1. Dip a loop of wire in a solution of CuSO4.
  2. Heat the loop in an oxidizing flame until it is red hot.
  3. Observe the color of the bead. If it turns blue-green, this indicates the presence of copper.

The chemical reactions involved are:

2CuSO4 + 6Na2B4O7 → Cu3B2O6 + 2Na2SO4 + 10NaBO2 CuSO4 → CuO + SO3

The blue-green color is due to the combination of the blue color of copper borate and the green color of copper oxide.

This problem has been solved

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