The freezing point of water is 0 o C at 1 atm pressure. Is the solid to liquid phasetransition of water spontaneous or reversible at this temperature?
Question
The freezing point of water is 0 °C at 1 atm pressure. Is the solid to liquid phase transition of water spontaneous or reversible at this temperature?
Solution
The solid to liquid phase transition of water at 0 degrees Celsius and 1 atm pressure is reversible. This is because at this specific temperature and pressure, water can exist in both solid (ice) and liquid (water) states. This is known as the melting point of ice or the freezing point of water.
If you add heat (energy) to ice at this condition, it will absorb the heat and melt to become water, which is a spontaneous process. However, if you remove heat from the water at this condition, it will release the heat and freeze to become ice, which is also a spontaneous process.
Therefore, the phase transition is reversible because it can go in both directions (from solid to liquid and from liquid to solid) depending on whether heat is added or removed.
However, it's important to note that the term "spontaneous" in thermodynamics has a specific meaning. A process is said to be spontaneous if it occurs without the need for a continuous input of energy. So in this context, while the phase transition can occur in both directions, each individual process (melting or freezing) is spontaneous under the right conditions.
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