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When treated with ammonia, acid chlorides are converted into which of the following?Select answer from the options belowAmidesCarboxylic acidsAminesAldehydes

Question

When treated with ammonia, acid chlorides are converted into which of the following?

Select answer from the options below:

  • Amides
  • Carboxylic acids
  • Amines
  • Aldehydes
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Solution

When acid chlorides are treated with ammonia (NH₃), they undergo a nucleophilic acyl substitution reaction. In this reaction, ammonia acts as a nucleophile and attacks the electrophilic carbon atom of the acid chloride, leading to the formation of an intermediate. This intermediate can then rearrange to eliminate hydrochloric acid (HCl), resulting in the formation of an amide.

Thus, the correct answer is Amides.

Explanation:

  1. Reactivity of Acid Chlorides: Acid chlorides are highly reactive due to the presence of the electrophilic carbonyl carbon and the good leaving group (Cl).
  2. Nucleophilic Attack: When ammonia is introduced, the nitrogen in ammonia has a lone pair that allows it to attack the carbonyl carbon, forming a tetrahedral intermediate.
  3. Dehydration: The tetrahedral intermediate collapses, leading to the elimination of HCl, which completes the formation of an amide.

Therefore, the conversion of acid chlorides with ammonia yields amides as the primary product.

This problem has been solved

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