Estimate the crystallite size of the given nanomaterial using p-XRD data:Peak position θ = 10.81o, FWHM of sample = 1.8o, k = 0.88 and λ = 1.54 Å
Question
Estimate the crystallite size of the given nanomaterial using p-XRD data:
- Peak position (θ) = 10.81°
- FWHM of sample = 1.8°
- k = 0.88
- λ = 1.54 Å
Solution
To estimate the crystallite size of the given nanomaterial using p-XRD data, we can use the Scherrer equation:
D = kλ / (β cos θ)
where: D is the crystallite size, k is the shape factor (dimensionless), usually taken as 0.9, λ is the X-ray wavelength, β is the full width at half maximum (FWHM) in radians, θ is the Bragg angle in radians.
Given: Peak position θ = 10.81o, FWHM of sample = 1.8o, k = 0.88, λ = 1.54 Å.
First, we need to convert the angles from degrees to radians. We know that π radians = 180 degrees. So, to convert degrees to radians, we multiply by π/180.
θ = 10.81 * π/180 = 0.1886 radians, β = 1.8 * π/180 = 0.0314 radians.
Now, we can substitute these values into the Scherrer equation:
D = 0.88 * 1.54 / (0.0314 * cos(0.1886)) = 44.8 Å.
So, the estimated crystallite size of the given nanomaterial is approximately 44.8 Å.
Similar Questions
If k = 0.1, lambda = 10 angstroms, cos theta= 15, FWHM of the xrd peak is 10 then grain size of the crystal is *1 point0.00660.00550.00440.0061
11. Magnesium crystallizes in a hexagonal close-packed (HCP) structure with an atomic mass of 24.305 g/mol, density of 1.74 g/cm³, and unit cell volume of 45.2 ų. Determine the number of atoms per unit cell. 12. Lead forms a face-centered cubic (FCC) structure with an atomic mass of 207.2 g/mol. If the density of lead is 11.34 g/cm³, calculate the atomic radius (in nm). 13. Rhodium crystallizes in a face-centered cubic (FCC) structure with an atomic radius of 135 pm. If its unit cell has a volume of 0.071 nm³, determine the density of rhodium in g/cm³. 14. Zinc crystallizes in a hexagonal close-packed (HCP) structure with a density of 7.14 g/cm³ and an atomic radius of 134 pm. Calculate the unit cell volume (in ų) of zinc. 15. Chromium crystallizes in a body-centered cubic (BCC) structure with a density of 7.19 g/cm³ and unit cell edge length of 2.88 Å. Determine the number of atoms per unit cell and verify the structure.
Which technique can be used for studying crystal structures of nanomaterials?Question 1Answera.AFMb.XRDc.SEMd.FTIRe.TEM
The standard kilogram is a platinum – iridium cylinder39.0 mm in height and 39.0 mm in diameter. What isthe density of the material?
How much energy does an X-ray with an 8 nm (8 × 10-9 m) wavelength have?A.8.28 × 10-26 JB.2.48 × 10-17 JC.1.99 × 10-25 JD.3.33 × 1016 J
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.