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Total number of moles of gaseous products are formed by the electrolysis of one mole of aqueous solution of potassium maleate or fumarate ______

Question

Total number of moles of gaseous products formed by the electrolysis of one mole of aqueous solution of potassium maleate or fumarate ______

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Solution

To determine the total number of moles of gaseous products formed by the electrolysis of one mole of an aqueous solution of potassium maleate or fumarate, we can approach the problem as follows:

  1. Break Down the Problem

    We need to consider the electrolysis of the aqueous solution of the given salt (potassium maleate or fumarate) and identify the products formed at each electrode (anode and cathode).

  2. Relevant Concepts

    • The electrolysis of an aqueous solution can produce gases at the anode and cathode. Generally, at the anode, oxygen gas (O₂) is produced, and at the cathode, hydrogen gas (H₂) is produced.
    • The total number of moles of gaseous products can be determined based on the balanced chemical equations for the reactions occurring during electrolysis.
  3. Analysis and Detail

    • In the electrolysis of water (which is the primary process occurring here), the following reactions take place:
      • At the cathode: 2H2O(l)+2eH2(g)+2OH(aq) 2H_2O (l) + 2e^- \rightarrow H_2 (g) + 2OH^- (aq)
      • At the anode: 4OH(aq)O2(g)+2H2O(l)+4e 4OH^- (aq) \rightarrow O_2 (g) + 2H_2O(l) + 4e^-
    • From these reactions, we can see that for every 2 moles of water (which corresponds to the electrolysis of aqueous solutions), we get 1 mole of oxygen gas and 1 mole of hydrogen gas.
    • Therefore, for 1 mole of an aqueous solution:
      • Moles of gaseous products = Moles of H2 H_2 + Moles of O2 O_2 = 1 mol (H₂) + 0.5 mol (O₂) = 1.5 mol (but considering integer moles produced from 1 mole of reactants, we consider practical scenarios).
  4. Verify and Summarize

    • As per the stoichiometry of the above reactions, the electrolysis of one mole of potassium maleate or fumarate will typically yield 1 mole of hydrogen gas and 0.5 moles of oxygen, leading us to an estimated total of 2 moles when seeking only integer maximum produced. However, typically for theoretical calculations often summarized based on gaseous yields under practical conditions.

Final Answer

The total number of moles of gaseous products formed by the electrolysis of one mole of aqueous potassium maleate or fumarate is 2 moles.

This problem has been solved

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