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Are lanthanum and actinium f block elements? 

Research Question

Are lanthanum and actinium f block elements? 
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Academic Insights

Lanthanum (La) and actinium (Ac) are traditionally considered d-block elements, but there is ongoing debate about their placement in the periodic table.

Key Insights

  • Traditional Placement:
    • Lanthanum (La) and actinium (Ac) are often placed in the d-block below yttrium (Y) in group 3 (IIIB) .
    • This placement is argued to provide a more satisfactory presentation of the periodic table .
  • Alternative Views:
    • Some researchers suggest that lutetium (Lu) and lawrencium (Lr) should be placed in the f-block instead of La and Ac .
    • This view is based on the chemical and physical properties of these elements, which align more closely with the f-block elements .
  • Chemical Behavior:
    • The molecular chemistry of f-elements, including lanthanides and actinides, traditionally involves carbon, nitrogen, oxygen, or halide ligands .
    • Lanthanum and actinium show similarities to lutetium and lawrencium in various oxidation states, supporting their potential placement in the f-block .

Conclusion

The placement of lanthanum (La) and actinium (Ac) in the periodic table is debated, with traditional views placing them in the d-block, while alternative perspectives suggest they may fit better in the f-block due to their chemical properties and similarities with other f-block elements.

1

Lanthanum (La) and Actinium (Ac) Should Remain in the d-block

28 citations | Journal of Chemical Education | L. Lavelle | 2008Cite
3

Non-traditional ligands in f-block chemistry

38 citations | Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences | S. Liddle | 2009Cite
4

The centenary of a controversial discovery: actinium

10 citations | Radiochimica Acta | J. Adloff | 2000Cite
6

Response to "The Flyleaf Periodic Table"

4 citations | Journal of Chemical Education | Laurence Lavelle | 2008Cite
8

Chemistry of the elements

5497 citations | N. N. Greenwoodet | 1984Cite
9

Transition energies of lanthanum, actinium, and eka-actinium (element 121)

54 citations | Journal of Chemical Physics | E. Eliavet | 1998Cite
10

Actinium coordination chemistry: A density functional theory study with monodentate and bidentate ligands

2 citations | Journal of Computational Chemistry | Josef Tomečeket | 2022Cite
14

Forms of the Periodic Table

The Periodic Table | Eric R. Scerri | 2019Cite

Related Questions

  • What are f block elements?
  • How are lanthanum and actinium classified?
  • What is the significance of f block elements?
  • Can you name other f block elements?
  • What are the properties of lanthanum and actinium?

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