Are lanthanum and actinium f block elements?
Research Question
Academic Insights
Lanthanum (La) and actinium (Ac) are traditionally considered d-block elements, but there is ongoing debate about their placement in the periodic table.
Key Insights
- Traditional Placement:
- Lanthanum (La) and actinium (Ac) are often placed in the d-block below yttrium (Y) in group 3 (IIIB) .
- This placement is argued to provide a more satisfactory presentation of the periodic table .
- Alternative Views:
- Some researchers suggest that lutetium (Lu) and lawrencium (Lr) should be placed in the f-block instead of La and Ac .
- This view is based on the chemical and physical properties of these elements, which align more closely with the f-block elements .
- Chemical Behavior:
- The molecular chemistry of f-elements, including lanthanides and actinides, traditionally involves carbon, nitrogen, oxygen, or halide ligands .
- Lanthanum and actinium show similarities to lutetium and lawrencium in various oxidation states, supporting their potential placement in the f-block .
Conclusion
The placement of lanthanum (La) and actinium (Ac) in the periodic table is debated, with traditional views placing them in the d-block, while alternative perspectives suggest they may fit better in the f-block due to their chemical properties and similarities with other f-block elements.
Lanthanum (La) and Actinium (Ac) Should Remain in the d-block
Non-traditional ligands in f-block chemistry
The centenary of a controversial discovery: actinium
Theoretical investigation of M@Pb122- and M@Sn122- Zintl clusters (M = Lrn+, Lun+, La3+, Ac3+ and n = 0, 1, 2, 3).
Response to "The Flyleaf Periodic Table"
Studies of Actinium(III) in Various Solutions. II. Distribution Behavior of Lanthanum(III) and Actinium(III) in Some Chelate Extraction Systems
Transition energies of lanthanum, actinium, and eka-actinium (element 121)
Actinium coordination chemistry: A density functional theory study with monodentate and bidentate ligands
Optimization of Cation Exchange for the Separation of Actinium-225 from Radioactive Thorium, Radium-223 and Other Metals
Update of Atomic Data for the First Three Spectra of Actinium
Progress and Recent Strategies in the Synthesis and Catalytic Applications of Perovskites Based on Lanthanum and Aluminum
Related Questions
- What are f block elements?
- How are lanthanum and actinium classified?
- What is the significance of f block elements?
- Can you name other f block elements?
- What are the properties of lanthanum and actinium?
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