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The energy transition (expressed in terms of vibrational energy levels) that gives rise to the absorbance at 1600 cm-1 is likely to be:

Question

The energy transition (expressed in terms of vibrational energy levels) that gives rise to the absorbance at 1600 cm⁻¹ is likely to be:

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Solution

The absorbance at 1600 cm-1 typically corresponds to the vibrational energy levels of a carbon-carbon double bond (C=C) or a carbon-oxygen double bond (C=O) in a molecule. This is because these bonds have similar bond strengths and masses, leading to similar vibrational frequencies.

Here are the steps to determine this:

  1. Identify the frequency of the transition: In this case, it's given as 1600 cm-1.

  2. Compare this frequency to known absorption frequencies of different types of bonds. Infrared (IR) spectroscopy tables are often used for this purpose.

  3. The frequency of 1600 cm-1 falls in the range of frequencies typically absorbed by C=C and C=O bonds during their vibrational transitions.

  4. Therefore, the energy transition that gives rise to the absorbance at 1600 cm-1 is likely to be a vibrational transition in a C=C or C=O bond.

Please note that this is a general answer and the exact bond could be determined by considering other factors such as the molecular structure, presence of other functional groups, etc.

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