The equivalent conductivity of 0.1 N CH3COOH at 25 °C is 80 and at infinite dilution 400. The degree of dissociation of CH3COOH is :10.10.20.5
Question
The equivalent conductivity of 0.1 N CH₃COOH at 25 °C is 80 and at infinite dilution 400. The degree of dissociation of CH₃COOH is :
- 0.10
- 0.20
- 0.5
Solution
1. Break Down the Problem
We need to calculate the degree of dissociation () of acetic acid (CHCOOH). Given data includes:
- Equivalent conductivity () of 0.1 N solution = 80 S cm²/mol
- Equivalent conductivity at infinite dilution () = 400 S cm²/mol
2. Relevant Concepts
The degree of dissociation for a weak electrolyte can be calculated using the formula:
where:
- is the equivalent conductivity at the given concentration,
- is the equivalent conductivity at infinite dilution.
3. Analysis and Detail
Substituting the values into the equation:
Now, we can perform the calculation:
4. Verify and Summarize
The calculation shows that the degree of dissociation of acetic acid in this scenario is 0.2, indicating that 20% of the acetic acid molecules dissociate in solution.
Final Answer
The degree of dissociation of CHCOOH is or .
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