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The equivalent conductivity of 0.1 N CH3COOH at 25 °C is 80 and at infinite dilution 400. The degree of dissociation of CH3COOH is :10.10.20.5

Question

The equivalent conductivity of 0.1 N CH₃COOH at 25 °C is 80 and at infinite dilution 400. The degree of dissociation of CH₃COOH is :

  • 0.10
  • 0.20
  • 0.5
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Solution

1. Break Down the Problem

We need to calculate the degree of dissociation (α\alpha) of acetic acid (CH3_3COOH). Given data includes:

  • Equivalent conductivity (Λc\Lambda_c) of 0.1 N solution = 80 S cm²/mol
  • Equivalent conductivity at infinite dilution (Λ0\Lambda_0) = 400 S cm²/mol

2. Relevant Concepts

The degree of dissociation for a weak electrolyte can be calculated using the formula:

α=ΛcΛ0 \alpha = \frac{\Lambda_c}{\Lambda_0}

where:

  • Λc\Lambda_c is the equivalent conductivity at the given concentration,
  • Λ0\Lambda_0 is the equivalent conductivity at infinite dilution.

3. Analysis and Detail

Substituting the values into the equation:

α=80400 \alpha = \frac{80}{400}

Now, we can perform the calculation:

α=0.2 \alpha = 0.2

4. Verify and Summarize

The calculation shows that the degree of dissociation of acetic acid in this scenario is 0.2, indicating that 20% of the acetic acid molecules dissociate in solution.

Final Answer

The degree of dissociation of CH3_3COOH is 0.20.2 or 20%20\%.

This problem has been solved

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