Where would you expect a carboxylic acid carbonyl signals to appear in a 13C NMR spectrum
Question
Where would you expect a carboxylic acid carbonyl signals to appear in a 13C NMR spectrum?
Solution
In a 13C NMR spectrum, the carbonyl carbon of carboxylic acids typically appears downfield, meaning it resonates at a lower field strength compared to more shielded carbon environments. Generally, you can expect the carbonyl signal of a carboxylic acid to fall within the range of 160 to 185 ppm.
This downfield shift occurs due to the deshielding effect caused by the electronegative oxygen atoms in the carbonyl group (C=O). The exact position can vary depending on factors such as hydrogen bonding, the presence of other electronegative groups, and the solvent used, but this range serves as a good guideline for interpreting 13C NMR spectra of carboxylic acids.
In summary, carboxylic acid carbonyl signals will appear between 160 and 185 ppm in a 13C NMR spectrum, indicative of the unique electronic environment surrounding the carbonyl carbon in these compounds.
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