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How would you distinguish experimentally between an alcohol anda carboxylic acid

Question

How would you distinguish experimentally between an alcohol and a carboxylic acid?

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Solution

To distinguish experimentally between an alcohol and a carboxylic acid, you can use the following steps:

  1. Litmus Test: Carboxylic acids will turn blue litmus paper red because they are acidic. Alcohols will not have any effect on the color of the litmus paper.

  2. Sodium Bicarbonate Test: Carboxylic acids react with sodium bicarbonate to produce carbon dioxide gas, which can be observed as effervescence. Alcohols do not react with sodium bicarbonate and will not produce any gas.

  3. Esterification Test: Carboxylic acids react with alcohols in the presence of a strong acid catalyst to form esters (pleasant smelling compounds). If you have a mixture of an unknown and an alcohol, and you smell a fruity aroma after adding a few drops of concentrated sulfuric acid and heating, then the unknown is a carboxylic acid. If no smell is detected, the unknown is likely an alcohol.

  4. Sodium Metal Test: Alcohols react with sodium metal to produce hydrogen gas and a sodium alkoxide. Carboxylic acids do not react with sodium metal.

Remember to always follow safety procedures when conducting these tests, including wearing appropriate personal protective equipment.

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