Identify the correct Lewis structure of CCl4. Ensure that all charges and lone pairs are shown.
Question
Identify the correct Lewis structure of CCl4. Ensure that all charges and lone pairs are shown.
Solution
To determine the correct Lewis structure of carbon tetrachloride (CCl₄), follow these steps:
1. Break Down the Problem
- Identify the elements involved: Carbon (C) and Chlorine (Cl).
- Determine the number of bonds and lone pairs present based on valence electrons.
2. Relevant Concepts
- Carbon is in group 14 and has 4 valence electrons.
- Chlorine is in group 17 and has 7 valence electrons.
- The total number of valence electrons in CCl₄ = 4 (from C) + 4 × 7 (from 4 Cl) = 4 + 28 = 32 electrons.
3. Analysis and Detail
-
Carbon will be the central atom since it can form four bonds.
-
Each chlorine will form a single bond with carbon. Thus, C will have 4 Cl atoms each forming a single bond:
-
After forming four single bonds, Carbon will have 0 lone pairs, and each Chlorine will have 3 lone pairs:
- For each Cl:
- 1 bond (shared with C)
- 3 lone pairs (6 electrons remaining for each Cl)
- For each Cl:
4. Verify and Summarize
- Verify that all atoms achieve a stable electron configuration:
- Carbon has 8 electrons (4 bonds).
- Each chlorine has 8 electrons (1 bond + 6 from lone pairs).
This confirms a stable structure with all atoms fulfilling the octet rule.
Final Answer
The Lewis structure of CCl₄ is represented as follows:
Cl
|
Cl - C - Cl
|
Cl
Where each chlorine (Cl) atom has three lone pairs around it, while carbon (C) is at the center with four single bonds to each chlorine atom.
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