an organic compound has relative moleculaf mass of 150 and contains 72.0% carbon, 6.67% hydrogen and 21.33% oxygen.Determine the emphirical formula
Question
An organic compound has relative molecular mass of 150 and contains 72.0% carbon, 6.67% hydrogen and 21.33% oxygen. Determine the empirical formula.
Solution
To determine the empirical formula, follow these steps:
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Assume you have 100g of the compound. This means you have 72g of Carbon (C), 6.67g of Hydrogen (H), and 21.33g of Oxygen (O).
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Convert these amounts into moles. Use the atomic masses of C, H, and O which are approximately 12g/mol, 1g/mol, and 16g/mol respectively.
Moles of C = 72g / 12g/mol = 6 moles Moles of H = 6.67g / 1g/mol = 6.67 moles Moles of O = 21.33g / 16g/mol = 1.33 moles
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Divide each of the calculated moles by the smallest number of moles calculated in step 2 to get the ratio of the atoms. In this case, the smallest number of moles is 1.33.
Ratio of C = 6 / 1.33 = 4.5 ≈ 5 (rounded to the nearest whole number) Ratio of H = 6.67 / 1.33 = 5 Ratio of O = 1.33 / 1.33 = 1
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The empirical formula of the compound is therefore C5H5O1, or simply C5H5O.
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