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Ksp of CaF2 is 1.7  10-10 and its mol. wt. is 78 g mole-1. What volume of the saturated solution will contain 0.078 g of CaF2?

Question

Ksp of CaF2 is 1.7  10<sup>-10</sup> and its mol. wt. is 78 g mole<sup>-1</sup>. What volume of the saturated solution will contain 0.078 g of CaF2?

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Solution

Sure, let's solve this step by step:

  1. First, we need to find the molar concentration of CaF2 in the saturated solution. The Ksp of CaF2 is given as 1.7 x 10^-10. The dissolution of CaF2 can be represented as:

    CaF2 (s) ⇌ Ca2+ (aq) + 2F- (aq)

    The Ksp expression for this reaction is:

    Ksp = [Ca2+][F-]^2

    Since the stoichiometric ratio of CaF2 to Ca2+ and F- is 1:1:2, the concentration of Ca2+ and F- in the saturated solution will be the same, let's call it 's'. So, the Ksp expression becomes:

    Ksp = s * (2s)^2 = 4s^3

    Solving for 's' gives:

    s = (Ksp / 4)^(1/3) = (1.7 x 10^-10 / 4)^(1/3) = 1.3 x 10^-3 M

  2. Now, we need to find the volume of the saturated solution that will contain 0.078 g of CaF2. First, convert the mass of CaF2 to moles using its molar mass:

    Moles of CaF2 = 0.078 g / 78 g/mole = 0.001 mole

  3. Then, use the molar concentration of CaF2 in the saturated solution to find the volume:

    Volume = moles / concentration = 0.001 mole / 1.3 x 10^-3 M = 0.77 L or 770 mL

So, 770 mL of the saturated solution will contain 0.078 g of CaF2.

This problem has been solved

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