Match the definition with the word.causing intense annoyance or angerdutifulgallingintricatestout

To match the definition "causing intense annoyance or anger," the appropriate word is galling.

Here's a brief overview of the other words for clarity:

1. Dutiful - Performing one's duties or obligations with a sense of responsibility.
2. Gall - To irritate greatly; also refers to bold and impudent behavior.
3. Intricate - Very detailed or complicated; involves many interconnected parts.
4. Stout - Strongly built or thick; can also mean courageous or determined.

Thus, the word that corresponds to the definition provided is galling.