What can be inferred from the magnetic moment values of the following complex species?Example Magnetic Moment (BM)K4[Mn(CN)6] 2.2[Fe(H2O)6]2+ 5.3K2[MnCl4] 5.9
Question
What can be inferred from the magnetic moment values of the following complex species?
Example Magnetic Moment (BM)
- K4[Mn(CN)6]: 2.2
- [Fe(H2O)6]2+: 5.3
- K2[MnCl4]: 5.9
Solution
The magnetic moment values of a complex species can give us information about the number of unpaired electrons in the species. This is because the magnetic moment is related to the number of unpaired electrons through the formula:
μ = √(n(n+2)) Bohr Magneton (BM)
where n is the number of unpaired electrons.
-
K4[Mn(CN)6] has a magnetic moment of 2.2 BM. This suggests that it has 1 unpaired electron. This is consistent with the fact that Mn in this complex is in the +2 oxidation state, which gives it a d5 configuration. One of these 5 electrons is unpaired.
-
[Fe(H2O)6]2+ has a magnetic moment of 5.3 BM. This suggests that it has 5 unpaired electrons. This is consistent with the fact that Fe in this complex is in the +2 oxidation state, which gives it a d6 configuration. Five of these 6 electrons are unpaired.
-
K2[MnCl4] has a magnetic moment of 5.9 BM. This suggests that it has 5 unpaired electrons. This is consistent with the fact that Mn in this complex is in the +2 oxidation state, which gives it a d5 configuration. All 5 of these electrons are unpaired.
In summary, the magnetic moment values of these complex species suggest that they have 1, 5, and 5 unpaired electrons respectively.
Similar Questions
Amongst the following ions? Which one has the highest magnetic moment value: (i) [Cr(H2O)6]3+ (ii) [Fe(H2O)6]2+ (iii) [Zn(H2O)6]2+
In which compound does manganese have a +6 oxidation number?A.MnOB.MnO2C.K2MnO4D.KMnO4
Among [Ni(CO)4], [NiCl4]2–, [Co(NH3)4Cl2]Cl, Na3[CoF6], Na2O2 and CsO2, the total number of paramagnetic species is
what are the special cases in spin magnetic moment of transition metals and their examples
Which of the following oxidation states of manganese could exhibit the greatest paramagnetism?Select one:a.Mn(II)b.Mn(III)c.Mn(IV)d.Mn(VII)
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.