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[Fe(CN)6]3– should be an inner orbital complex. Ignoring the pairing energy, the value of crystal field stabilization energy for this complex is (-) _______ Δ

Question

[Fe(CN)6]3– should be an inner orbital complex. Ignoring the pairing energy, the value of crystal field stabilization energy for this complex is (-) _______ Δ
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Solution 1

The complex [Fe(CN)6]3– is indeed an inner orbital or low spin complex. This is because CN- is a strong field ligand and it causes the pairing of electrons in the 3d orbitals of Fe.

The Fe in [Fe(CN)6]3– is in the +3 oxidation state. Therefore, it has 5 electrons in the 3d orbitals.

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