For the reactionN2O4⇌2NO2(g), the degree of dissociation at equilibrium is 0.2 at 1 atm. ThenKpwill be1/21/41/6
Question
For the reaction
N₂O₄ ⇌ 2NO₂(g), the degree of dissociation at equilibrium is 0.2 at 1 atm. Then Kp will be
1/2
1/4
1/6
Solution
To find the value of Kp for the reaction N2O4 ⇌ 2NO2(g), we need to use the given degree of dissociation at equilibrium, which is 0.2.
Step 1: Write the balanced equation for the reaction: N2O4 ⇌ 2NO2(g)
Step 2: Define the equilibrium expression using the concentrations of the reactants and products: Kp = [NO2]^2 / [N2O4]
Step 3: Since the degree of dissociation at equilibrium is 0.2, we can assume that 0.2 moles of N2O4 dissociate to form 0.2 moles of NO2. Therefore, the concentrations at equilibrium are: [N2O4] = (initial concentration of N2O4) - (0.2 moles) [NO2] = (initial concentration of NO2) + (0.2 moles)
Step 4: Substitute the equilibrium concentrations into the equilibrium expression: Kp = ([NO2] + 0.2)^2 / ([N2O4] - 0.2)
Step 5: Since the reaction is at 1 atm, we can assume that the initial pressure of N2O4 is equal to the equilibrium pressure. Therefore, the initial concentration of N2O4 is equal to the initial pressure divided by the ideal gas constant (R) and the temperature (T): [N2O4] = (1 atm) / (R * T)
Step 6: Substitute the initial concentration of N2O4 into the equilibrium expression: Kp = ([NO2] + 0.2)^2 / ((1 atm) / (R * T) - 0.2)
Step 7: Simplify the expression if necessary.
Unfortunately, without specific values for the temperature and the ideal gas constant, we cannot calculate the exact value of Kp.
Similar Questions
For the reactionN2O4⇌2NO2(g), the degree of dissociation at equilibrium is 0.2 at 1 atm. ThenKpwill be1/21/41/6
The standard free energy change (ΔG°) for 50% dissociation of N2O4 into NO2 at 27 °C and 1 atm pressure is −x J mol−1 . The value of x
The equilibrium constant, KC, for the following reaction is 2.5 × 10-3N2(g) + O2(g) ⇌ 2NO(g)If [N2]eq = 0.75 M and [NO]eq = 0.090, then [O2]eq
There is a right shift of the O2 dissociation curve under all of the following conditions, exceptHigh pCO2High H+High temperatureHigh pH
Consider the following reaction at 298 K.32O2( g)⇌O3( g)⋅KP=2.47×10−29.ΔrG⊕ for the reaction is _______ kJ. (Given R =8.314JK−1 mol−1)
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.