The normal heat of fusion of water is 18.53 J/mol. Calculate the change of entropy of the system that 1 mole of solid water is changed to liquid water?
Question
The normal heat of fusion of water is 18.53 J/mol. Calculate the change of entropy of the system that 1 mole of solid water is changed to liquid water?
Solution
To calculate the change in entropy (ΔS) when 1 mole of solid water changes to liquid water, we can use the formula:
ΔS = q/T
where:
- q is the heat absorbed or released during the phase change (in this case, the heat of fusion), and
- T is the absolute temperature (in Kelvin).
The heat of fusion (q) is given as 18.53 J/mol.
However, we don't have the temperature (T) given in the problem. The temperature at which water melts (i.e., changes from solid to liquid) is 0 degrees Celsius, which is equivalent to 273.15 Kelvin.
So, we can substitute these values into the formula:
ΔS = (18.53 J/mol) / (273.15 K)
This gives us:
ΔS = 0.0678 J/(mol*K)
So, the change in entropy when 1 mole of solid water changes to liquid water is 0.0678 J/(mol*K).
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