Among the following, the state function(s) is(are)internal energyGibbs energyreversible expansion workmolar enthalpy
Question
Among the following, the state function(s) is(are)
- internal energy
- Gibbs energy
- reversible expansion work
- molar enthalpy
Solution
To identify which of the given options are state functions, let’s clarify what a state function is. A state function is a property of a system that depends only on the current state of the system, not on how it reached that state. Examples include internal energy, enthalpy, and Gibbs energy.
Analysis of the Options:
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Internal Energy: This is a state function. It is a measure of the total energy of a thermodynamic system and depends only on the state of the system.
-
Gibbs Energy: Also known as Gibbs free energy, this is a state function. It represents the maximum reversible work that can be performed by a thermodynamic system at constant temperature and pressure.
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Reversible Expansion Work: This is not a state function. It depends on the specific process and path taken during the expansion, not just the starting and ending states.
-
Molar Enthalpy: This is a state function as well. Enthalpy is defined for a specific state and, like internal energy and Gibbs energy, it's a potential energy of the system.
Final Answer:
The state functions among the options are:
- Internal Energy
- Gibbs Energy
- Molar Enthalpy
Reversible expansion work is not a state function.
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