If the change in free energy (ΔG) is , the reaction is spontaneous under the conditions specified. If ΔG is , the reaction is not spontaneous.
Question
If the change in free energy (ΔG) is ΔG < 0
, the reaction is spontaneous under the conditions specified.
If ΔG > 0
, the reaction is not spontaneous.
Solution
The change in free energy (ΔG) is a crucial concept in thermodynamics, particularly in predicting whether a chemical reaction will occur spontaneously under a given set of conditions.
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Definitions:
- Spontaneous Reaction: A reaction that will proceed without any external influence. This typically occurs when ΔG < 0.
- Non-Spontaneous Reaction: A reaction that will not occur without external influence. This occurs when ΔG > 0.
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Interpreting ΔG:
- If ΔG < 0: This indicates that the products of the reaction have lower free energy than the reactants, leading to a release of energy, thus making the reaction spontaneous.
- If ΔG > 0: This suggests that the products possess higher free energy than the reactants, implying that energy must be supplied for the reaction to occur, making it non-spontaneous.
In summary, a negative ΔG indicates spontaneity of a reaction, while a positive ΔG indicates non-spontaneity. If ΔG is equal to zero, the system is in equilibrium, meaning no net change is occurring.
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