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Which of the following is used to convert a nitrile to a carboxylic acid?Select answer from the options belowROHAqueous acidLiAlH4Pyridinium chlorochromate

Question

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Solution

To convert a nitrile to a carboxylic acid, the correct reagent is aqueous acid.

Explanation:

  1. Mechanism: Nitriles (R-C≡N) can be hydrolyzed to carboxylic acids (R-COOH) through a process involving the addition of water (hydrolysis) in the presence of an acid catalyst.
  2. Reagents: The nitrile is treated with a strong acid (such as hydrochloric acid) and water, which facilitates the addition of a water molecule to the nitrile and ultimately transforms it into a carboxylic acid.
  3. Incorrect Options:
    • ROH (alcohol) is not effective for this transformation.
    • LiAlH4 is a strong reducing agent that typically reduces nitriles to primary amines, not carboxylic acids.
    • Pyridinium chlorochromate is used for oxidation reactions and would not be suitable for this reaction.

Final Answer:

The correct answer is aqueous acid.

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