What would be the major product of the following reaction?C6H5 -CH2-OC6H5 + HBr A + B
Question
What would be the major product of the following reaction?
C6H5 -CH2-OC6H5 + HBr → A + B
Solution
The reaction given is between benzyl phenyl ether and hydrobromic acid (HBr). This is an example of an ether cleavage reaction.
Step 1: Protonation of the ether The reaction begins with the protonation of the oxygen atom in the ether by the hydrobromic acid. This makes the oxygen a good leaving group.
C6H5-CH2-O-C6H5 + HBr -> C6H5-CH2-OH2(+)-C6H5 + Br(-)
Step 2: Cleavage of the C-O bond The C-O bond is cleaved, and the oxygen takes the pair of electrons. This results in the formation of a carbocation and a phenol.
C6H5-CH2-OH2(+)-C6H5 -> C6H5-CH2(+) + C6H5-OH
Step 3: Reaction of the carbocation with bromide The carbocation reacts with the bromide ion to form the final product.
C6H5-CH2(+) + Br(-) -> C6H5-CH2-Br
So, the major products of the reaction are bromobenzene (C6H5-CH2-Br) and phenol (C6H5-OH).
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